Journal
APPLIED CATALYSIS B-ENVIRONMENTAL
Volume 96, Issue 3-4, Pages 239-244Publisher
ELSEVIER
DOI: 10.1016/j.apcatb.2010.02.030
Keywords
Ag doping; TiO2; CO2 reduction; Photocatalysis
Funding
- Czech Ministry of Education, Youth and Sports [MSM 6198910019]
- Program Nanotechnology for Society [KAN400720701]
- Grant Agency of the Czech Republic [203/08/H032]
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Pure TiO2 and various silver-enriched TiO2 powders were prepared by the sol-gel process controlled in the reverse micellar environment. The catalysts were tested in CO2 photocatalytic reduction and characterized by X-ray diffraction (XRD), nitrogen adsorption measurement and UV-vis. Methane and methanol were the main reduction products. The yield of methane and methanol increases when modifying the TiO2 by silver incorporation is caused by two mechanisms: up to 5% of Ag in TiO2 the Ag impurity band inside the TiO2 bandgap decreases the absorption edge and increases so the electron-hole pair generation, above 5% of Ag in TiO2 Ag metallic clusters are formed in TiO2 crystals with Shottky barrier at the metal-semiconductor interface, which spatially separates electron and holes and increases their lifetime (decreases probability of their recombination). (C) 2010 Elsevier B.V. All rights reserved.
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