Journal
TETRAHEDRON LETTERS
Volume 46, Issue 23, Pages 3981-3985Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2005.04.036
Keywords
copper; asymmetric catalysis; phosphino-phenol; conjugate addition
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Newly designed phosphino-phenol 1c was found to be an efficient chiral auxiliary for copper-mediated asymmetric conjugate addition of diethylzine to acyclic enones. High enantio selectivity up to > 99% ee was achieved in the reaction of acyclic alpha,beta-enones. (c) 2005 Elsevier Ltd. All rights reserved.
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