Journal
FEBS LETTERS
Volume 579, Issue 14, Pages 3081-3084Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.febslet.2005.04.066
Keywords
photosynthesis; photosystem II; water oxidation; oxygen evolution; manganese; EPR
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Ammonia and methanol both bind to the water oxidising complex of photosystem II during its turnover, possibly at sites where water binds during the normal water oxidation process. We have investigated the interaction between these two water analogues at the S-2 state of the water oxidising cycle using electron magnetic resonance techniques. We find evidence that ammonia displaces methanol from its binding site. (c) 2005 Published by Elsevier B.V. on behalf of the Federation of European Biochemical Societies.
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