Journal
APPLIED CATALYSIS B-ENVIRONMENTAL
Volume 92, Issue 1-2, Pages 61-67Publisher
ELSEVIER
DOI: 10.1016/j.apcatb.2009.07.024
Keywords
Mesoporous; Titania; Phosphorus; Nitrogen; Photoactivity
Funding
- National Natural Science Foundation of China [20473041, 20673060]
- National Basic Research Program of China [2009CB623502]
- Specialized Research Fund for the Doctoral Program of Higher Education [20070055014]
- Natural Science Foundation of Tianjin [08JCZDJC21500]
- Chinese-Bulgarian Scientific and Technological Cooperation Project
- Hebei Provincial Department of Education [2007313]
- Program for New Century Excellent Talents in University [NCET-06-0215]
- Nankai University
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Hierarchical mesoporous P- and N-doped titanias were synthesized by the direct phosphation from phosphoric acid and the following nitridation with urea solution. The resulting materials were characterized by XRD, nitrogen adsorption, SEM, TEM, UV-vis, FT-IR and XPS analysis, and their photocatalytic activities were tested by the visible-light photodegradation of Rhodamine B solution. A bimodal mesopore size distribution with a macroporous structure was observed, rendering high surface area with thermal stability. N-doping of the hierarchical mesoporous titania resulted in the band-gap narrowing with improved photocatalytic activity. However, the phosphated titania exhibited higher photocatalytic activity than the N-doped one, but with larger band-gap energy. Further nitridation of phosphated titania resulted in narrower band-gap of the N,P-codoped titania than either N- or P-doped one, exhibiting the further enhanced photocatalytic activity. (C) 2009 Elsevier B.V. All rights reserved.
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