Journal
ORGANIC LETTERS
Volume 7, Issue 12, Pages 2345-2348Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol050573m
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We have developed a convenient and straightforward procedure for the preparation of functionalized 3,4-ethylenedioxythiophene (EDOT) systems by using a new chloromethyl-EDOT derivative as a versatile synthon. Based on this procedure, novel suitably functionalized perylenetetracarboxylic diimide (PDI) dye derivatives covalently linked to 3,4-ethylenedioxythiophene moieties have been synthesized and electrochemically polymerized to yield a donor-acceptor PENT derivative with an enhanced absorption cross-section.
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