Journal
ORGANIC LETTERS
Volume 7, Issue 12, Pages 2333-2335Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol050556x
Keywords
-
Categories
Ask authors/readers for more resources
A novel chiral monodentate spiro phenylphospholane ligand 4 was prepared from a readily accessible, enantiomerically pure 1,1 '-spirobiindane-7,7 '-diol in high yield. This ligand has proven to be efficient for Pd-catalyzed enantioselective allylation of aldehydes with allylic alcohols. Aromatic, heteroaromatic, and aliphatic aldehydes gave homoallylic alcohols in good enantioselectivities (up to 83% ee) and excellent anti diastereoselectivities (up to 99:1 dr).
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available