4.8 Article

Iridium-catalyzed ring cleavage reaction of cyclobutanone O-benzoyloximes providing nitriles

Journal

ORGANIC LETTERS
Volume 7, Issue 12, Pages 2425-2427

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol0507120

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[GRAPHICS] Iridium-catalyzed ring cleavage reaction of cyclobutanone O-benzoyloximes in the presence of 9,10-dihydroanthracene and potassium carbonate proceeds to give saturated nitriles via C-C bond fission at the sterically more hindered site.

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