Journal
ORGANIC LETTERS
Volume 7, Issue 12, Pages 2433-2435Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol050734m
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[GRAPHICS] The highly enantioselective synthesis of 2-aryl-4-piperidones by rhodium/phosphoramidite-catalyzed conjugate addition of arylboroxines to 2,3-dihydro-4-pyridones is described. Both enantiomers of a variety of products with sterically and electronically different R substituents were obtained in high isolated yield and with excellent enantioselectivity up to 99%.
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