Journal
CHEMISTRY OF MATERIALS
Volume 17, Issue 12, Pages 3108-3113Publisher
AMER CHEMICAL SOC
DOI: 10.1021/cm050394z
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We report on the first observation of quantum splitting effect in nanocrystalline powders of SrAl12O19:1 % Pr, Mg. The nanocrystalline materials were prepared using a surfactant-templated-assisted route yielding high-quality hexagonal nanocrystallites with thicknesses comprised between 30 and 60 nm. Comprehensive optical studies, including emission, photoexcitation, and time-resolved fluorescence measurements, demonstrate that no physical property degradation such as surface-induced loss mechanisms are found and that the quantum splitting properties of the material are fully retained in the nanocrystalline particles.
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