Journal
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
Volume 43, Issue 12, Pages 2615-2624Publisher
WILEY
DOI: 10.1002/pola.20750
Keywords
graft copolymers; hydrogels; reversible addition fragmentation chain transfer (RAFT)
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The comb-type grafted hydrogels poly(N-isopropylacrylamide)-g-poly(N-isopropylacrylamide) (PNIPAM-g-PNIPAM) and poly(acrylic acid)-g-poly(N-isopropylacrylamide) (PAAc-g-PNIPAM) were prepared by reversible addition-fragmentation chain transfer polymerization. A macromolecular chain-transfer agent was prepared first. Then, hydrogels were obtained by a reaction with a comonomer (N-isopropylacrylamide or acrylic acid) in the presence of N,N-methylenebisacrylamide as a crosslinker. The equilibrium swelling ratios and the swelling and deswelling kinetics of PNIPAM-g-PNIPAM were measured. The effects of the chain length and amount on the swelling behavior were investigated. The deswelling mechanism was illustrated. Meanwhile, the PAAc-g-PNIPAM hydrogel was used to confirm the versatility of this novel method. It was prepared in an alcoholic medium, whereas hydrogen-bonding complexes formed in 1,4-dioxane, which was chosen as the reaction medium for the PNIPAM-g-PNIPAM hydrogel. (c) 2005 Wiley Periodicals, Inc.
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