Journal
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume 690, Issue 12, Pages 3095-3098Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2005.03.032
Keywords
hydroformylation; paraformaldehyde; olefins; rhodium; phosphine
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The hydroformylation of medium-chain C6 olefins and of allyl alcohol was achieved with paraformaldehyde in dioxane solution using rhodium catalysts with mono-, bi-, and tri-dentate phosphine ligands. The highest activities with n/i ratios around 2, were obtained for a system derived from [Rh(dppe)(2)]*, prepared in situ by reaction of Rh(acac)(CO)2 with 2 eq of dppe. (c) 2005 Elsevier B.V. All rights reserved.
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