Journal
APPLIED CATALYSIS A-GENERAL
Volume 570, Issue -, Pages 387-394Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.apcata.2018.07.041
Keywords
Diesel vehicles; Selective catalytic reduction; Soot combustion; Combined catalysts
Categories
Funding
- National NaturalScience Foundation of China [21603213, 21677139]
- Changchun Science and Technology Bureau [17DY004]
- Youth Innovation Promotion Association of Chinese Academy of Sciences, China [2018263]
- Development Program of the Science and Technology Department of Jilin Province [20180201088GX]
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Pt@CeO2/MCM-56 (PCM) and CeO2-CuO (9:1)/MCM-56 (CCM) were combined to purify the exhaust emissions from diesel vehicles in three configuration statuses, defined as configuration A-where CCM stays above PCM, configuration B-where PCM stays above CCM, and configuration C-where CCM mixes with PCM homogeneously in loose contact. Among these combined catalysts, the configuration A is most favorable for the selective catalytic reduction (SCR) reaction, with > 80% NOx conversion obtained at the temperature range of 150-550 degrees C and gas hourly space velocity (GHSV) of 240,000 ml g(-1) h(-1). NH3-TPD, H2-TPR and NH3 conversion measurements demonstrated that NH3 can be selectively used to reduce NOx in the configuration A but is over oxidized if the reaction is operated in configuration B or configuration C status, deteriorating the deNO(x) activity at temperature above 250 degrees C. Hence, configuration A not only takes advantage but also overcomes the shortcomings of PCM and CCM, leading to high NOx conversion and N-2 selectivity. A significant decrease in the onset temperature of soot combustion was also observed in this research.
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