Journal
TETRAHEDRON LETTERS
Volume 46, Issue 25, Pages 4279-4282Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2005.04.092
Keywords
iridium-catalyzed double incorporation reaction; C-H bond activation; precoordination to olefin
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Reaction of styrene with N-benzylmaleimide in the presence of[IrCl(cod)](2) (5 mol%) and bpy (10 mol%) in an autoclave (1 MPa of Ar) at 150 degrees C for 18 h stercoselectively led to the formation of a new cyclic product. The structure of the product Suggests that a novel iridium-catalyzed double incorporation reaction takes place via a metallacyclopentane formed after ortho-C-H activation. (c) 2005 Elsevier Ltd. All rights reserved.
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