Journal
ORGANOMETALLICS
Volume 24, Issue 13, Pages 3047-3052Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om050148x
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The complexation of the uncommon 1-zirconacyclopent-3-yne Cp2Zr(eta(4)-H2C4H2) by Ni(0) complexes is described and compared to the coordination of similar 1-metallacyclopenta-2,3,4-trienes Cp2M(eta(4)-PhC4Ph) of titanium and zirconium, both showing mu-cis-complexation of 1,2,3-butatrienes and 1,3-butadiynes in addition to the well-known mu-trans-complexation.
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