Journal
ORGANIC LETTERS
Volume 7, Issue 13, Pages 2631-2634Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol050744n
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Efficient photorelease (Phi = 0.7) of carboxylic acids is achieved with a covalently linked mediator (benzophenone) protecting group (N-alkyl-4-picolinium ester) molecule. The mechanism involves initial photoreduction of the mediator, followed by rapid electron transfer to the protecting group.
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