Journal
ORGANIC LETTERS
Volume 7, Issue 13, Pages 2579-2582Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol050694m
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An operationally simple and mild protocol for the catalytic enantioselective epoxiclation of alpha,beta-unsaturated ketones has been estabilished using commercially available a,a-diphenyl-L-prolinol as bifunctional organocatalyst and tert-butyl hydroperoxide (TBHP) as oxidant. The epoxides have been obtained in good yields and with up to 80% ee.
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