Journal
ORGANIC LETTERS
Volume 7, Issue 13, Pages 2603-2606Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol0507064
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The binding tendencies toward carboxylates of a trifurcated receptor containing three copper(II)-cyclam subunits have been investigated in pure water, through the displacement of a fluorescent indicator. The receptor is tailor-made for the recognition of tricarboxylates, e.g., citrate, whose three negatively charged oxygen atoms interact with the three coordinatively unsaturated CuII centers.
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