Journal
TETRAHEDRON LETTERS
Volume 46, Issue 26, Pages 4501-4503Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2005.04.123
Keywords
monolayer; gold cluster; Ru-carbene complex; metathesis
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Monolayer-protected gold cluster (Au-MPC)-bound Ru-carbene complex (MPC-7) has been synthesized and examined its catalytic activity in ring-closing olefin metathesis. The MPC-7 showed almost the same catalytic activity with that of simple molecules (Grubbs Ru-complex 1b and the thioacetate-functionalized Ru-complex 8) and reused several times. (c) 2005 Elsevier Ltd. All rights reserved.
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