4.6 Article

Alcohol amination with heterogeneous ruthenium hydroxyapatite catalysts

Journal

APPLIED CATALYSIS A-GENERAL
Volume 469, Issue -, Pages 191-197

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/j.apcata.2013.09.051

Keywords

Amination; Ruthenium; Hydroxyapatite; N-alkylation; Borrowing hydrogen

Funding

  1. Fund for Scientific Research Flanders (FWO-Vlaanderen)
  2. IWT-Vlaanderen
  3. Belgian Science Policy (BELSPO) [IAP-PAI P7/05]
  4. Flemish government

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The intermolecular amination of alcohols was performed with ruthenium (Ru3+) immobilized on a calcium hydroxyapatite support. No additional base additives were necessary, nor did the catalyst require base treatment prior to reaction. High conversions were obtained with different amine and alcohol reactants. (C) 2013 Elsevier B.V. All rights reserved.

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