Journal
INORGANIC CHEMISTRY
Volume 44, Issue 13, Pages 4445-4447Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic050324u
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Mixed (difluoro)phenylpyridine/(difluoro)phenylpyrazole tris-cyclometalated iridium complexes were prepared in order to study the effect of fluorination and the pyridine/pyrazole ratio on the emission and electrochemical properties. Increasing fluorination and replacement of pyridine by pyrazole both leads to a widening of the HOMO-LUMO gap and generally leads to a blue shift in emission.
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