Journal
ELECTROCHIMICA ACTA
Volume 50, Issue 19, Pages 3897-3903Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2005.02.065
Keywords
polymer electrolyte; nanocomposite; mechanical properties; thermal properties
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Nanocomposite polymer electrolytes based on high-molecular weight poly(oxyethylene) (POE) were prepared from high aspect ratio cellulosic whiskers and lithium trifluoromethyl sulfonyl imide (LiTFSI). Prior to the polymer electrolyte characterization, the polymer/whiskers nanocomposites were characterized using wide-angle X-ray scattering (WAXS), differential scanning calorimetry (DSC) and dynamic mechanical analysis (DMA). Interactions between cellulose and POE were evidenced. The main effect of the filler was a thermal stabilization of the storage modulus for the composites above the melting point of the complexes POE/LiTFSI. The ionic conductivity was quite consistent with the specifications of lithium batteries. (c) 2005 Elsevier Ltd. All rights reserved.
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