Journal
APPLIED CATALYSIS A-GENERAL
Volume 455, Issue -, Pages 247-260Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.apcata.2013.01.021
Keywords
Silica; Heterogeneous; Palladium; Polyethylenimine; Catalysis
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Funding
- University Grants Commission (UGC), New Delhi under Meritorious Fellowship Scheme
- Department of Science and Technology (DST), New Delhi
- University Grants Commission-Basic Scientific Research (UGC-BSR), New Delhi
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We present the use of amine-functionalized silica (NH2-SiO2) as support for palladium nanoparticles (PdNPs) and the use of heterogeneous catalysts (Pd/NH2-SiO2) for the Suzuki, Heck and Sonogashira coupling reactions. The synthesized Pd catalyst is well characterized by XRD, HRTEM, BET, SEM-EDX, FT-IR, and UV-vis spectral techniques. It exhibits efficient catalytic activity for these coupling reactions without the assistance of ligand and copper salts. (c) 2013 Elsevier B.V. All rights reserved.
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