Journal
APPLIED CATALYSIS A-GENERAL
Volume 443, Issue -, Pages 138-144Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.apcata.2012.07.033
Keywords
MoS2/CdS; Ball-milling; Photocatalyst; H-2 evolution; Visible light irradiation
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Funding
- National Natural Science Foundation of China [20725311, 21173260, 51072221]
- National Basic Research Program of China (973) [2012CB932903]
- Knowledge Innovation Program of the Chinese Academy of Sciences [KJCX2-YW-W27]
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A simple and effective ball-milling combined calcination method has been developed to prepare MoS2/CdS photocatalysts for visible-light-driven water splitting into H-2 for the first time. The photo-cataysts exhibit very high photocatalytic activities. A H-2 evolution rate up to 1315 mu mol h(-1) has been achieved based on 0.9 mol% MoS2/CdS (FT) photocatalyst (PT is the abbreviation of pretreatment), which is much higher than 488 mu mol h(-1) for the 0.2 wt% Pt/CdS (PT) photocatalyst. In the meantime, this photocatalyst exhibits good anti-photocorrosion property. The ball-milling procedure makes the starting material, (NH4)(2)MoS4, disperse uniformly on the surface of CdS nanoparticles. Further calcination treatment leads to complete decomposition of (NH4)(2)MoS4 to afford MoS2/CdS photocatalysts with intimate contacts between the two components. The pretreatment of CdS also has important positive effect on photocatalytic activity. Similar reactions by attempting different kinds of commercial CdS products have been carried out, indicating this preparation method is universal. (C) 2012 Elsevier B.V. All rights reserved.
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