4.6 Article

Solvent-free selective aerobic oxidation of toluene by ultra fine nano-palladium catalyst

Journal

APPLIED CATALYSIS A-GENERAL
Volume 415, Issue -, Pages 47-52

Publisher

ELSEVIER
DOI: 10.1016/j.apcata.2011.12.008

Keywords

Nano-palladium catalyst; Solvent-free; Toluene aerobic oxidation; Heterogeneous catalysis

Funding

  1. National Nature Scientific Foundation of China [21076044]
  2. Southeast University [21076044]

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High activity ultrafine Pd catalyst was synthesized by both functional polymer encapsulated and impregnation methods. Catalysts were characterized and used to catalyze solvent-free aerobic toluene oxidation. Reaction temperature, time, catalyst mass, air pressure and catalyst reusability were investigated. Catalyst synthesized by encapsulating and immobilizing Pd inside titanium oxide is more active and has a better reusability. (C) 2011 Elsevier B.V. All rights reserved.

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