Journal
CURRENT ORGANIC SYNTHESIS
Volume 2, Issue 3, Pages 301-331Publisher
BENTHAM SCIENCE PUBL LTD
DOI: 10.2174/1570179054368527
Keywords
stereochemistry; alkaloids; pictet-spengler; bischier-napieralski; enantiomers; diastereomers
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Various aspects of stereoselective synthesis of tetrahydroisoquinolines and tetrahydro-beta-carbolines with the use of natural compounds as chirality sources are reviewed. The following low molecular weight substrates are considered: carbohydrates, isoprenoids, hydroxyacids, alkaloids and amino acids. Examples of various synthetic methodologies that employ the above derivatives as chiral building blocks. chiral auxiliaries or chiral ligands are presented.
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