Journal
INORGANIC CHEMISTRY COMMUNICATIONS
Volume 8, Issue 7, Pages 585-587Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.inoche.2005.03.025
Keywords
tantalum(V); beta-diketonate; eight coordinate cation
Categories
Ask authors/readers for more resources
Reaction of TaCl5 with neat tmhdH (2,2,6,6-tetramethylheptane-3,5-dione) (in the absence of solvent) yields the ionic compound [Ta(tmhd)(4)] [TaCl6]. This complex contains the eight coordinate Ta(V) cation, [Ta(tmhd)(4)](+), accompanied by the hexachlorotantalate anion, [TaCl6](-). This is the first complex of tantalum in the +5 oxidation state containing four chelating diketonate anions to be characterised using X-ray crystallography. (c) 2005 Elsevier B.V. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available