Journal
RUSSIAN CHEMICAL BULLETIN
Volume 54, Issue 7, Pages 1593-1598Publisher
SPRINGER
DOI: 10.1007/s11172-006-0008-6
Keywords
electrolysis; electrocatalytic transformation; dialkyl malonates; arylidenemalononitriles; alkylidenemalononitriles; mediators; substituted cyclopropanes
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Electrolysis of alcoholic solutions of dialkyl malonates and arylidene- or alkylidenemalononitriles in the presence of NaBr in an undivided cell gave dialkyl esters of 3-substituted 2,2-dicyanocyclopropane-1,1-dicarboxylic acids in 60-90% yields.
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