Journal
APPLIED CATALYSIS A-GENERAL
Volume 392, Issue 1-2, Pages 28-35Publisher
ELSEVIER
DOI: 10.1016/j.apcata.2010.10.026
Keywords
Oxidation; Hydrogen peroxide; Fe; Mn; Supported metal-substituted; polyoxometalates
Categories
Funding
- University of Aveiro
- FCT (Fundacao para a Ciencia e a Tecnologia)
- FEDER
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The preparation and characterization (FT-IR, FT-Raman, diffuse reflectance, elemental analysis) of novel catalysts with iron or manganese substituted polyoxotungstates [XMIII(H2O)W11O39](n-) (X = P, M = Fe or Mn; X = Si or B, M = Fe) immobilized on a functionalized silica matrix are reported. The new materials were tested as heterogeneous catalysts in the oxidation of cis-cyclooctene and cyclooctane at 80 degrees C, using environmentally safe hydrogen peroxide as oxidant and acetonitrile as solvent. Some of these novel heterogeneous catalysts could be reused several times without appreciable loss of catalytic activity. (C) 2010 Elsevier B.V. All rights reserved.
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