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Conventional synthesis methods of short-chain dialkylcarbonates and novel production technology via direct route from alcohol and waste CO2

Journal

APPLIED CATALYSIS A-GENERAL
Volume 383, Issue 1-2, Pages 1-13

Publisher

ELSEVIER
DOI: 10.1016/j.apcata.2010.05.046

Keywords

Dimethyl carbonate; Diethyl carbonate; Carbon dioxide; Zirconia; Palladium-copper chloride

Funding

  1. Academy of Finland [129170]
  2. Umea University
  3. Kempe foundations
  4. Knut & Alice Wallenberg foundation
  5. Academy of Finland (AKA) [129170, 129170] Funding Source: Academy of Finland (AKA)

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The aim of this work is to review different synthesis methods of dialkylcarbonates with special emphasis on diethyl carbonate synthesis methodologies. The novel synthesis route for dimethyl carbonate and diethyl carbonate based on the utilization of alcohol and carbon dioxide as the raw materials, together with heterogeneous catalysts, is presented. (C) 2010 Elsevier B.V. All rights reserved.

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