Journal
PROGRESS IN POLYMER SCIENCE
Volume 30, Issue 7, Pages 725-782Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.progpolymsci.2005.04.001
Keywords
triblock terpolymers; linear; miktoarm star; cyclic; synthesis; living polymerization; living/controlled polymerizations; self-assembly; selective solvents; bulk
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The synthesis of linear and non-linear (star, cyclic) triblock terpolymers through living, controlled/living polymerization methods and their combinations are reviewed. The theoretical predictions and the experimental results concerning the self-assembly of these materials in selective solvents and in bulk are also discussed. A plethora of self-assembled structures have been detected either in solution or in bulk, potentially leading to a rich variety of high-tech applications. First results regarding the synthesis and morphology of multicomponent multiblock (tetrablock quarter and pentablock quinto) polymers are also given. (c) 2005 Elsevier Ltd. All rights reserved.
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