Journal
APPLIED CATALYSIS A-GENERAL
Volume 362, Issue 1-2, Pages 163-168Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.apcata.2009.04.038
Keywords
C-C coupling; Mizoroki-Heck Reaction; Biphenyl-based phosphine; Palladium catalyst
Categories
Funding
- Razi University Research Council
- Kermanshah Oil Refining Company
Ask authors/readers for more resources
An efficient and stereoselective catalytic system has been reported for the Mizoroki-Heck cross coupling using a moderately bulky and electron-rich biphenyl-based phosphine, P(o-C6H4C6H4Me)Ph-2 and a low Pd(OAc)(2) loading. It is found that the nature of olefin has more beneficial effect on the reaction times and yields than the aryl halide which may be due to more contribution of the coordination and/or insertion of the olefin in the rate-determining step of the Heck reaction. (C) 2009 Elsevier B.V. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available