Journal
RUSSIAN CHEMICAL BULLETIN
Volume 54, Issue 7, Pages 1632-1636Publisher
SPRINGER
DOI: 10.1007/s11172-006-0015-7
Keywords
transition metals; nickel complexes; phosphazanes; triazene; X-ray diffraction analysis
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3-(Diphenylphosphino)-1,3-diphenyltriazene Ph2P-NPh-N=NPh was synthesized. The reactions of this compound with bis(cycloocta-1,5-diene)nickel, (cod)(2)Ni, and nickel(I) bis(triphenylphosphino)bis(trimethylsilyl)amide, (Ph3P)(2)Ni-N(SiMe3)(2), afforded the anionic nickel complex [Ph4P](+)[Ni(PhNNNPh)(3) ](-) in 15 and 78% yields, respectively.
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