4.4 Article

A comparison between lime and alkaline hydrogen peroxide pretreatments of sugarcane bagasse for ethanol production

Journal

APPLIED BIOCHEMISTRY AND BIOTECHNOLOGY
Volume 148, Issue 1-3, Pages 45-58

Publisher

SPRINGER
DOI: 10.1007/s12010-008-8200-9

Keywords

lignocellulosic materials; sugarcane bagasse; pretreatment; lime; hydrogen peroxide; enzymatic hydrolysis; statistical analysis

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Pretreatment procedures of sugarcane bagasse with lime (calcium hydroxide) or alkaline hydrogen peroxide were evaluated and compared. Analyses were performed using 2 x 2 x 2 factorial designs, with pretreatment time, temperature, and lime loading and hydrogen peroxide concentration as factors. The responses evaluated were the yield of total reducing sugars (TRS) and glucose released from pretreated bagasse after enzymatic hydrolysis. Experiments were performed using the bagasse as it comes from an alcohol/sugar factory and bagasse in the size range of 0.248 to 1.397 mm (12-60 mesh). The results show that when hexoses and pentoses are of interest, lime should be the pretreatment agent chosen, as high TRS yields are obtained for nonscreened bagasse using 0.40 g lime/g dry biomass at 70 degrees C for 36 h. When the product of interest is glucose, the best results were obtained with lime pretreatment of screened bagasse. However, the results for alkaline peroxide and lime pretreatments of nonscreened bagasse are not very different.

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