Journal
TETRAHEDRON LETTERS
Volume 46, Issue 27, Pages 4643-4646Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2005.04.139
Keywords
-
Categories
Ask authors/readers for more resources
A method for the high-yielding preparation of two tridentate, isoquinoline-derived ligands, involving successive Suzuki cross-coupling reactions, is described. The first ligand Could be resolved via molecular complexation with N-benzylcinchonidinium chloride, while the second was resolved by chromatographic separation of its epimeric carnphorsulfonates. The barrier to rotation about the central biaryl axis was evaluated via racemisation Studies, and the absolute configuration assigned by X-ray crystallography. (c) 2005 Elsevier Ltd. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available