4.8 Article

Intramolecular cyclotrimerization of triynes catalyzed by N-heterocyclic carbene-CoCl2/Zn or -FeCl3/Zn

Journal

ORGANIC LETTERS
Volume 7, Issue 14, Pages 3065-3067

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol051048q

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Triynes 1 could effectively be cyclotrimerized to annulated benzenes 2 by treatment with a catalytic amount of zinc powder, N-heterocyclic carbene, and COCI2 or FeCI3.

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