Journal
ORGANIC LETTERS
Volume 7, Issue 14, Pages 3111-3114Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol0511833
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The richly oxygenated C(1)-C(30) polyol segment of amphidinol 3 has been synthesized in protected form. Incorporated in this long chain are 10 of the 25 stereogenic centers housed in the target. The asymmetric pathway that has been developed is based on the efficient union of three independently prepared subunits.
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