Journal
ORGANIC LETTERS
Volume 7, Issue 14, Pages 3001-3004Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol050979z
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A gold(I) complex of Xantphos AuCl(xantphos) catalyzes the dehydrogenative silylation of alcohols with high chemoselectivity and solvent tolerance. It is selective for the silylation of hydroxyl groups in the presence of alkenes, alkynes, alkyl halides (RCl, RBr), ketones, aldehydes, conjugated enones, esters, and carbamates.
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