Journal
ORGANIC LETTERS
Volume 7, Issue 14, Pages 3093-3096Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol051114o
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An effective generation of indium hydride (HInCl2) under nonacidic conditions is achieved by transmetalation between Ph2SiH2 and InCl2OMe. The presented system achieves the titled coupling reactions in a radical manner. In particular, the nonacidic character enables the applications to acid-sensitive inter- and intramolecular ene-yne couplings.
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