Journal
ORGANIC LETTERS
Volume 7, Issue 14, Pages 3123-3125Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol051216e
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The use of air-stable, electron-rich phosphine oxides as preligands allows for unprecedented general ruthenium-catalyzed arylation reactions of pyridines and imines through C-H-bond activation using aryl chlorides. The catalytic system derived from a sterically hindered adamantyl-substituted phosphine oxide proves highly efficient and tolerates a number of important functional groups.
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