Journal
INORGANIC CHEMISTRY
Volume 44, Issue 14, Pages 4912-4914Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic050452i
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The reaction of Zn(NO3)(2)-6H(2)O, various dicarboxylic acids, and either 4,4'-bipyridine or N,N'-di(4-pyridyl)-1,4,5,8-naphthalenetetracarboxydiimide produces a family of anisotropic, mixed-ligand, open-framework compounds featuring paddle-wheel-type coordination of Zn(II) pairs in two dimensions and pyridyl ligand pillaring in the third. Despite 2-fold interpenetration, the compounds contain channels of molecular dimensions and several are permanently microporous, displaying high internal surface areas.
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