Journal
TETRAHEDRON
Volume 61, Issue 29, Pages 6982-6987Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2005.05.022
Keywords
N-sulfinylper(poly)fluoroalkanesulfinamide; hetero Diels-Alder reaction; diene
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N-Sulfinylper(poly)fluoroalkanesulfinamides reacted readily with dienes in methylene chloride at -78 degrees C to give the corresponding cycloadducts with complete regioselectivities and good diastereoselectivities. The diastereoselectivity of the reaction was switchable to the opposite under the catalysis of Lewis acids such as TiCl4 and SnCl4. (c) 2005 Elsevier Ltd. All rights reserved.
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