Journal
ORGANIC LETTERS
Volume 7, Issue 15, Pages 3371-3373Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol051276k
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- NIGMS NIH HHS [GM 64451] Funding Source: Medline
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The catalytic stereoselective Oshima-Utimoto reaction is useful for the construction of five-membered oxacycles from simple starting materials and was employed for the preparation of the lactone group in the asymmetric synthesis of (-)-11 alpha,13-dihydroxanthatin. Completion of the synthesis is facilitated by ring-closing enyne metathesis and alkene cross metathesis reactions.
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