Journal
MACROMOLECULAR RAPID COMMUNICATIONS
Volume 26, Issue 14, Pages 1179-1184Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/marc.200500192
Keywords
atom transfer radical polymerization (ATRP); fullerenes; poly(tert-butyl acrylate) (PtBA); telechelics; water-soluble polymers
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A multistep synthetic procedure for preparing novel C-60-anchored two-armed poly(tert-butyl acrylate) was developed. First, two-armed poly(tert-butyl acrylate) bearing a malonate ester core with well-controlled molecular weight was synthesized through atom transfer radical polymerization. The effective Bingel reaction between C-60 and the well-defined polymer was then carried out to yield C60-anchored polymer. GPC, H-1 NMR, and UV-vis spectroscopy indicated that the C60-anchored polymer was a monosubstituted and 'closed' 6,6-ring-bridged methanofullerene derivative.
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