4.7 Article

Are defect models consistent with the entropy and specific heat of glass formers?

Journal

JOURNAL OF CHEMICAL PHYSICS
Volume 123, Issue 4, Pages -

Publisher

AMER INST PHYSICS
DOI: 10.1063/1.1955527

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We show that pointlike defect model of glasses cannot explain the thermodynamic properties of glass formers, as for example, the excess specific heat close to the glass transition, contrary to the claim of Garrahan and Chandler [Proc. Natl. Acad. Sci. U.S.A. 100, 9710 (2003)]. More general models and approaches in terms of extended defects are also discussed. (C) 2005 American Institute of Physics.

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