Journal
SCIENCE
Volume 309, Issue 5734, Pages 591-594Publisher
AMER ASSOC ADVANCEMENT SCIENCE
DOI: 10.1126/science.1112767
Keywords
-
Categories
Ask authors/readers for more resources
We describe a new strategy for the in situ growth of molecular wires predicated on the synthesis of a trifunctional primed contact formed from metal-carbon multiple bonds. The ruthenium-carbon it bond provides structural stability to the molecular linkages under ambient conditions, and density functional calculations indicate the formation of an efficient conduit for charge carriers to pass between the metal and the molecule. Moreover, the metal-carbon it bond provides a chemically reactive site from which a conjugated molecular wire can be grown in situ through an olefin metathesis reaction.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available