Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2005, Issue 15, Pages 3173-3176Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.200500226
Keywords
amine; cross coupling; C-H activation; C-CN bond cleavage; copper catalyst
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A novel and efficient C-C bond-formation method was developed: the cross-dehydrogenative coupling (CDC) reaction catalyzed by copper bromide in the presence of an oxidizing reagent, tBuOOH. The CDC reaction provides a simple and efficient catalytic method to construct beta-amino diesters and beta-dicyano amines by a combination of two different sp(3) C-H bonds followed by C-C bond formation. (c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005).
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