Journal
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume 690, Issue 15, Pages 3585-3599Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2005.04.009
Keywords
supported catalysts; olefin metathesis; ionic liquid
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New recyclable imidazolium-tagged ruthenium catalysts have been developed to perform olefin metathesis in room temperature ionic liquids (RTILs). High level of recyclability combined with a high reactivity were obtained in the ring-closing metathesis (RCM) of a variety of di- or tri-substituted and/or oxygen-containing dienes. Extremely low residual ruthenium levels were detected in the RCM products (average of 7.3 ppm per run). Several examples of olefin cross-metathesis (CM) have been also studied. (c) 2005 Elsevier B.V. All rights reserved.
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