Journal
ORGANOMETALLICS
Volume 24, Issue 16, Pages 4083-4086Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om0580203
Keywords
-
Categories
Ask authors/readers for more resources
The prolonged reaction of [Rh{B(mt)(3)}(eta 4C8H12)]Cl, prepared from [Rh(eta(4)-C8H12)Cl](2) and 2 equiv of Na(HB(mt)(3)], with a further excess of Na[HB(mt)(3)] leads to formation of the first binuclear metallaboratrane salt, [Rh-2[B(mt)(3)](2){kappa(2)-S,S'-HB(mt)(3)})Cl. This compound, which is also observed as a decomposition product of rhodium tris(methimazolyl)borane complexes, affords the first evidence for bridging of transition metals by the methimazolyl sulfur donors.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available