Journal
LETTERS IN ORGANIC CHEMISTRY
Volume 2, Issue 5, Pages 469-474Publisher
BENTHAM SCIENCE PUBL LTD
DOI: 10.2174/1570178054405968
Keywords
aromaticity; arsenic; heterocycles; small ring systems; quantum chemistry
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Using quantum chemical methodology, we reinvestigate the aromaticity of the much debated arsole, using the newly developed gauge-including magnetically induced currents (GIMIC) method. GIMIC provides a quantitative measure of the induced ring current strength, showing arsole to be moderately aromatic. Comparison is made. with pyrrole, phosphole, and cyclopentadiene.
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