Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 347, Issue 10, Pages 1325-1328Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200505113
Keywords
carbon dioxide fixation; copolymerization; green chemistry; homogeneous catalysis; ligand design
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New 3-amino-2-cyanoimidoacrylate ligands with varying steric demands have been synthesized. Zinc acetate complexes of these ligands catalyze the copolymerisation Of CO2 and cyclohexene oxide, showing high activities (TOF up to over 200 h (-1)).
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